1
20.06
LITHIUM-ION RECHARGEABLE BATTERY
Li-ion
Prismatic Lithium-ion
Rechargeable Battery
Danger
Do not dip or wet the battery in water, seawater, or other liquid.
Otherwise the battery may be shorted, which may generate heat
or cause damage.
Do not put the battery into a fire. Otherwise, the electrolyte may
burn or cause an explosion.
Do not heat the battery. Otherwise the electrolyte may gasify and
resin parts may melt, causing leakage, explosion or fire.
The battery has a predetermined polarity. If the battery will not
connect well to the charger or equipment, do not try to connect
the battery forcefully. Check the polarity first. If the battery is
connected in reverse, it will be charged in reverse and may cause
leakage, heat generation, explosion or fire due to an abnormal
chemical reaction.
Do not connect the battery in reverse relation to the positive (+)
and negative (–) terminals in the charger or equipment. If the
battery is connected in reverse, it will be charged in reverse,
discharge excessive current and may cause heat generation,
explosion or fire due to an abnormal chemical reaction.
Do not let the battery terminals (+ and –) come into contact with a
wire or any metal (like a metal necklace or a hairpin) with which it
is carried or stored. In such a case, the battery will be shorted and
discharge excessive current, which may result in heat generation,
explosion or fire.
Do not apply any heavy impact to the battery, throw or drop it.
Otherwise the battery may be shorted and result in heat
generation, explosion or fire.
Improper use of the battery may cause heat, fire, explosion, damage or
reduced battery capacity. Please read and follow the handling instructions
for the battery before and during usage. The followings are general
cautions and guidelines only and as such may not include every possible
usage scenario. The manufacturer will not be liable for actions taken or
accidents caused.
Secondary Battery
Start charge
Constant current, constant voltage charge
• Voltage monitoring
• Current monitoring
• Temperature monitoring
• Time monitoring
Failed
Failed
Passed
Passed
Select the correct type of battery to match the operating conditions
such as load current, etc.
The information in this section is for lithium-ion cells only. Maxell
offers these cells (excluding CLB) in battery pack format only.
These include electronic circuits to prevent overcharge,
overdischarge and so on. These battery packs are
custom-developed and produced according to special
requirements regarding operating conditions and specifications.
As a result, a minimum number of units may apply to such
customized orders from customers purchasing battery packs. For
details, consult your nearest Maxell dealer or distributor.
Charge conditions
To get the most out of lithium-ion batteries and use them safely,
please read the following requirements carefully:
Charge control flowchart (sample)
Refer to the following flowchart when designing constant
current and constant voltage battery chargers.
Charge mode
Constant current, constant voltage charge (CCCV)
Charge voltage
4.20±0.05V / cell, 4.35±0.05V / cell, 4.40±0.05V / cell
Max. charge current
1I
t
A
Charge temperature 0 to +45 deg. C
Check battery connection
Check battery temperature
Check battery voltage
Charge completion
Preliminary charge
Abnormal charge stop
Notes for Designers Safety Instructions
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Li-ion
20.06
• Insulate (+) and (–) terminals with tape.
• Do not remove coating.
• Do not expose to rain or water.
• Do not disassemble.
• Do not leave under strong sunshine.
• Store in rugged receptacle and cover with a lid.
Charge 0 deg. C to
+
45 deg. C
Discharge
20 deg. C to
+
60 deg. C
Storage (less than 30 days)
20 deg. C to
+
50 deg. C
Storage (less than 90 days)
20 deg. C to
+
35 deg. C
Notes for treating used batteries
Do not drive a nail into, hammer or stamp on the battery.
Otherwise the battery may be shorted and result in heat
generation, explosion or fire.
Do not solder the battery directly. Heat applied during soldering
may melt resin parts such as separator or gasket, and result in
leakage, heat generation, explosion or fire.
Do not disassemble or alter the battery. Otherwise the battery may
be shorted and result in heat generation or fire.
Do not use or leave the battery near fire, heaters, inside an
automobile in hot weather or under strong sunshine. Such
conditions of high temperature may damage the separator, and
the battery may be shorted and result in heat generation,
explosion or fire.
When charging the battery, do not use any battery charger not
specified by the manufacturer. Always follow the charge
conditions specified by the manufacturer. If the battery is charged
under other conditions (a high temperature, a high voltage/current
or an altered charger) not specified by the manufacturer, the
battery may cause heat generation, explosion or fire due to
abnormal chemical reactions.
Do not connect the battery directly to an electric outlet or cigarette
lighter socket in a car. Applying a high voltage may generate an
excessive current and cause an electric shock. In such a case, the
battery may leak electrolyte, overheat, explode or cause fire.
Do not put the battery in a microwave oven or a pressure cooker.
Sudden heat may damage the seal of the battery and may cause
heat generation, explosion or fire.
Do not use the battery together with a primary battery such as a
dry battery or other battery of a different capacity, type and/or
brand. In such a case, over-discharge during use or over-charge
during charging may occur and abnormal chemical reactions may
cause heat generation, explosion or fire from the battery.
If you notice any unusual odor, heat, discoloration, deformation or
any other characteristic apart from what you are used to while
using, charging or storing the battery, then take it out of the
equipment or charger, and avoid using it. Using it in such state
may result in heat generation, explosion or fire.
If the battery leaks or emits an unusual odor, remove it from the
vicinity of any fire immediately. The electrolyte may catch fire,
which may cause heat generation or explosion.
Do not let leaked electrolyte come into contact with the eyes. In
the event of such contact, flush the eyes with plenty of water
immediately and consult a doctor. Otherwise prolonged contact
may cause serious injury.
If the battery leaks and its electrolyte comes into contact with skin
or clothes, wash the contact area well with tap water or other
clean water right away. Otherwise skin may break out in a rash.
When the battery is expected not to be used for a long time, take
the battery out of the equipment or device and store it in a less
humid area.
After long periods of storage without being used, the battery
should be charged before it is used. Charge the battery every 6
months to the level specified by the manufacturer, even if the
battery is not used.
Do not leave the battery pack connected to the charger. It may
cause the degradation of battery performance, such as a
shortening of battery life.
Turn off your equipment or device power switch after use.
Remove the charged battery from the charger.
Do not recharge without using a charged battery (without
discharging at all). The battery may swell.
Do not use the battery in other than the following temperature
ranges:
Warnings
Caution
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Li-ion
20.06
0 120 30024060 180
4.5
4.0
3.5
3.0
2.5
2.0
0 1000 30002000 50004000
25 deg. C
–20 deg. C
60 deg. C
–10 deg. C
0 500 1000 45001500 2000 2500 35003000 4000
5000
4000
3000
2000
1000
Thin battery with high capacity
Maxell’s original technologies, such as electrode technology, have
realized thin batteries with high capacity that can be used in
compact high-performance mobile devices.
Stable discharge under various temperature conditions
Lithium-ion batteries provide stable discharge within a wide range of
temperatures, between –20 deg. C and 60 deg. C.
Excellent cost performance
Superior recharging properties ensure a service life of about 500
charge/discharge cycles under normal usage conditions. The
superior cost/performance ratio ensures that lithium-ion batteries are
ultimately more economical than primary batteries.
Higher energy density and an operating voltage of over 3.7V
A lithium-ion battery delivers and maintains a stable operating
voltage of over 3.7V until final discharge — three times as much
voltage as an Ni-Cd or Ni-MH battery provides. Therefore, it takes
only one-third as many lithium-ion batteries to provide the equivalent
amount of voltage as Ni-Cd or Ni-MH batteries provide. This means
that portable devices can be made much smaller and lighter.
Charge characteristics
Discharge load characteristics
Discharge temperature characteristics
Cycle life characteristics
Mobile phones, Smartphones Portable game devices
Electronic books Electronic dictionaries
Digital still cameras Digital audio players, etc.
Cell voltage (V)
Time (min)
100
80
60
40
20
0
Charge capacity (%)
Charge current (mA)
Cell voltage (V)
Capacity (mAh)
Cell voltage (V)
Capacity (mAh)
Features
Cell Structure
Applications
Characteristics (ICP616180AWR)
Laser seal
Negative terminal
Gas release vent
Positive can
Separators
Positive electrode
Negative electrode
Cycle number (cycle)
Capacity (mAh)
Charge current
Cell voltage
Charge: 4020mA (1I
t
A)/4.4V (CCCV)/3h
Temperature: 25 deg. C
Charge capacity
4.5
4.0
3.5
3.0
2.5
4.5
4.0
3.5
3.0
2.5
Charge: 4020mA (1I
t
A)/4.4V (CCCV)/3h
Discharge: 0.2I
t
A, 1I
t
A (E.V. = 2.75V)
Temperature: 25 deg. C
0 100 200 300 400 500
2.5
2.5
Charge: 4020mA (1I
t
A)/4.4V (CCCV)/3h
Discharge: 804mA (0.2I
t
A) (E.V. = 2.75V)
Temperature: 25 deg. C
0.2I
t
A (804mA)
1I
t
A (4200mA)
0
500
2000
1000
1500
2500
3000
3500
4500
4000
Charge: 4020mA (1I
t
A)/4.4V (CCCV)/3h
Discharge: 4020mA (1I
t
A) (E.V. = 2.75V)
Temperature: 25 deg. C