Specific hazards
Prolonged contact with air may cause formation of explosive peroxides. Direct sunlight or heat
may accelerate the release of peroxides. Rate of peroxide formation is not known. Burning
produces obnoxious and toxic fumes.
An environmental hazard cannot be excluded in the event of unprofes sio nal handling or dis posa l.
See ECOLOGICAL INFORMATION, Section 12.
Main symptoms
Harmful if swallowed. Symptoms may include pain, headache, nausea, vomiting, dizziness,
drowsiness and other central nervous system effects. May result in loss of consciousness and
nervous system damage.
Toxic in contact with skin or if inhaled Symptoms may include pain, headach e, naus ea, vomiting,
dizziness, drowsiness and other central nervous system effects. May result in loss of
consciousness, nervous system damage and possibly death.
May be mildly irritating to the skin and eyes. May cause redness and pain.
Product may present an aspiration hazard, if ingest ed in large amounts. Aspiration into the lungs
during swallowing or subsequent vomiting may cause chemical pneumonitis, which can be fatal.
2.2. Label elements
Label according to Regulation (EC) No. 1272/2008 as amended
Contains:
Acetylacetone
Hazard pictograms
Signal word
Danger
Hazard statements
H226
Flammable liquid and vapour.
H302
Harmful if swallowed.
H311 + H331
Toxic in contact with skin or if inhaled
Precautionary statements
Prevention
P210
Keep away from heat and open flames-No smoking.
P261
Avoid breathing vapours.
P280
Wear protective gloves/clothing and eye/face protection.
Response
P302 + P352
IF ON SKIN: Wash with plenty of soa p and water.
P301 + P312
IF SWALLOWED: Call a POISON CENTRE or doct or /p hy sic i an if you feel unwell.
P304 + P340
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Storage
Not assigned.
Disposal
P501
Dispose of contents/c ontainer in accordance with local/regional/national/international regulations.
Supplemental label information
None required according to Regulation (EC) No. 1272/2008.
2.3. Other hazards
Other hazards which do not result in classification:
Prolonged contact with air may cause formation of explosive peroxides. Direct sunlight or heat may
accelerate the release of peroxides. Rate of peroxide formation is not known. Burning produces
obnoxious and toxic fumes. May be mildly irritating to the skin and eyes. Product may present an
aspiration hazard, if ing ested in large amounts.
PBT assessment: Contains no substances, at reportable levels, considered to be persistent,
bioaccumulating nor toxic (PBT).
SECTION 3: Composition/information on ingredients
3.1. Substances
General information
Chemical name %
CAS-No. / EC No.
REACH Registration No. INDEX No.
Notes
Acetylacetone 99 - 100
123-54-6
204-634-0
Not available. 606-029-00-0
No additional
information.
Classification:
DSD:
CLP:
R10, Xn;R20/21/22
Flam. Liq. 3;H226, Acute Tox. 4;H302, Acute Tox. 3;H311, Acute Tox.
3;H331
CLP: Regulation No. 1272/2008.
DSD: Directive 67/548/EEC.
Composition comments
The full text for all R- and H-phrases is displayed in section 16.
Material name: CHO-SHIELD® 4994 Part C (Acetylacetone)
52-04-4994-1000, 52-03-4994-1000 Version No.: 01 Issue date: 30-May-2014
SDS EU
2 / 10